Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex

Terminal cobalt(IV)–oxo (Co(IV)–O) species have been implicated as key intermediates in various cobalt-mediated oxidation reactions. Herein we report the photocatalytic generation of a mononuclear non-haem [(13-TMC)Co(IV)(O)](2+) (2) by irradiating [Co(II)(13-TMC)(CF(3)SO(3))](+) (1) in the presence...

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Publicado no:Nat Commun
Main Authors: Wang, Bin, Lee, Yong-Min, Tcho, Woon-Young, Tussupbayev, Samat, Kim, Seoung-Tae, Kim, Yujeong, Seo, Mi Sook, Cho, Kyung-Bin, Dede, Yavuz, Keegan, Brenna C., Ogura, Takashi, Kim, Sun Hee, Ohta, Takehiro, Baik, Mu-Hyun, Ray, Kallol, Shearer, Jason, Nam, Wonwoo
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2017
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5376677/
https://ncbi.nlm.nih.gov/pubmed/28337985
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms14839
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