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One-pot palladium-catalyzed synthesis of sulfonyl fluorides from aryl bromides

A mild, efficient synthesis of sulfonyl fluorides from aryl and heteroaryl bromides utilizing palladium catalysis is described. The process involves the initial palladium-catalyzed sulfonylation of aryl bromides using DABSO as an SO(2) source, followed by in situ treatment of the resultant sulfinate...

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Vydáno v:Chem Sci
Hlavní autoři: Davies, Alyn T., Curto, John M., Bagley, Scott W., Willis, Michael C.
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2017
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5369543/
https://ncbi.nlm.nih.gov/pubmed/28451264
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc03924c
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