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The dual role of thiourea in the thiotrifluoromethylation of alkenes
Alkenes substituted with a thiourea undergo C–CF(3) followed by intramolecular C–S bond formation with the Togni reagent and trifluoroacetic acid (TFA) at room temperature; thiols and thioamides are not suitable S-sources for this reaction. This anti-addition process involves a CF(3) radical, and af...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5369526/ https://ncbi.nlm.nih.gov/pubmed/28451260 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02790c |
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