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Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into mole...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5365008/ https://ncbi.nlm.nih.gov/pubmed/28451338 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04893e |
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