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Using Ylide Functionalization to Stabilize Boron Cations
The metalated ylide YNa [Y=(Ph(3)PCSO(2)Tol)(−)] was employed as X,L‐donor ligand for the preparation of a series of boron cations. Treatment of the bis‐ylide functionalized borane Y(2)BH with different trityl salts or B(C(6)F(5))(3) for hydride abstraction readily results in the formation of the bi...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5363341/ https://ncbi.nlm.nih.gov/pubmed/28185370 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611677 |
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