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Protein chemical shifts arising from α-helices and β-sheets depend on solvent exposure

The NMR chemical shifts of certain atomic nuclei in proteins ((1)H(α),(13)C(α), and (13)C(β)) depend sensitively on whether or not the amino acid residue is part of a secondary structure (α-helix, β-sheet), and if so, whether it is helix or sheet. The physical origin of the different chemical shifts...

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Detalhes bibliográficos
Main Authors: Avbelj, Franc, Kocjan, Darko, Baldwin, Robert L.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2004
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC536043/
https://ncbi.nlm.nih.gov/pubmed/15574491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0407969101
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