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Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution
The comparison of experimental and predicted kinetic isotope effects in the α-cleavage of alkoxy radicals is used here to judge the applicability of statistical rate theories. It is found that the governing rate theory and the statistical versus nonstatistical nature of the cleavage depend on the cl...
Kaydedildi:
| Yayımlandı: | J Am Chem Soc |
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| Asıl Yazarlar: | , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2016
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5358507/ https://ncbi.nlm.nih.gov/pubmed/27764943 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09052 |
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