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Competition between Reaction and Intramolecular Energy Redistribution in Solution. Observation and Nature of Nonstatistical Dynamics in the Ozonolysis of Vinyl Ethers

Experimental product ratios in ozonolyses of alkyl vinyl ethers in solution do not fit with expectations from statistical rate theories. The selectivity among cleavage pathways increases with the size of the alkyl group but to an extent that is far less than RRKM theory would predict. Trajectory stu...

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Detalhes bibliográficos
Main Authors: Quijano, Larisa Mae M., Singleton, Daniel A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3164887/
https://ncbi.nlm.nih.gov/pubmed/21812422
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2043497
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