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Enantiospecific Intramolecular Heck Reactions of Secondary Benzylic Ethers

[Image: see text] Enantioenriched methylenecyclopentanes are synthesized by stereospecific, nickel-catalyzed Heck cyclizations of secondary benzylic ethers. The reaction proceeds in high yield and enantiospecificity for benzylic ethers of both π-extended and simple arenes. Ethers with pendant 1,2-di...

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Autors principals: Harris, Michael R., Konev, Mikhail O., Jarvo, Elizabeth R.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4063177/
https://ncbi.nlm.nih.gov/pubmed/24852707
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5026485
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