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Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C–H activation

Since our initial report in 1976, the oxygen rebound mechanism has become the consensus mechanistic feature for an expanding variety of enzymatic C–H functionalization reactions and small molecule biomimetic catalysts. For both the biotransformations and models, an initial hydrogen atom abstraction...

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Bibliografische gegevens
Gepubliceerd in:J Biol Inorg Chem
Hoofdauteurs: Huang, Xiongyi, Groves, John T.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Springer Berlin Heidelberg 2016
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5350257/
https://ncbi.nlm.nih.gov/pubmed/27909920
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-016-1414-3
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