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Site-selective (18)F fluorination of unactivated C–H bonds mediated by a manganese porphyrin
The first direct C–H (18)F fluorination reaction of unactivated aliphatic sites using no-carrier-added [(18)F]fluoride is reported. Under the influence of a manganese porphyrin/iodosylbenzene system, a variety of unactivated aliphatic C–H bonds can be selectively converted to C–(18)F bonds. The mild...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Royal Society of Chemistry
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5885592/ https://ncbi.nlm.nih.gov/pubmed/29675161 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04545j |
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