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Formation of novel transition metal hydride complexes with ninefold hydrogen coordination

Ninefold coordination of hydrogen is very rare, and has been observed in two different hydride complexes comprising rhenium and technetium. Herein, based on a theoretical/experimental approach, we present evidence for the formation of ninefold H- coordination hydride complexes of molybdenum ([MoH(9)...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Sci Rep
Prif Awduron: Takagi, Shigeyuki, Iijima, Yuki, Sato, Toyoto, Saitoh, Hiroyuki, Ikeda, Kazutaka, Otomo, Toshiya, Miwa, Kazutoshi, Ikeshoji, Tamio, Orimo, Shin-ichi
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Nature Publishing Group 2017
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5347150/
https://ncbi.nlm.nih.gov/pubmed/28287143
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep44253
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