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Formation of novel transition metal hydride complexes with ninefold hydrogen coordination

Ninefold coordination of hydrogen is very rare, and has been observed in two different hydride complexes comprising rhenium and technetium. Herein, based on a theoretical/experimental approach, we present evidence for the formation of ninefold H- coordination hydride complexes of molybdenum ([MoH(9)...

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Detalhes bibliográficos
Publicado no:Sci Rep
Main Authors: Takagi, Shigeyuki, Iijima, Yuki, Sato, Toyoto, Saitoh, Hiroyuki, Ikeda, Kazutaka, Otomo, Toshiya, Miwa, Kazutoshi, Ikeshoji, Tamio, Orimo, Shin-ichi
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2017
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5347150/
https://ncbi.nlm.nih.gov/pubmed/28287143
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep44253
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