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Nucleophile-Assisted Alkene Activation: Olefins Alone Are Often Incompetent

Emerging work on organocatalytic enantioselective halocyclizations naturally draws on conditions where both new bonds must be formed under delicate control, the reaction regime where the concerted nature of the Ad(E)3 mechanism is of greatest importance. Without assistance, many simple alkene substr...

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Detalles Bibliográficos
Publicado en:J Am Chem Soc
Autores principales: Ashtekar, Kumar Dilip, Vetticatt, Mathew, Yousefi, Roozbeh, Jackson, James E., Borhan, Babak
Formato: Artigo
Lenguaje:Inglês
Publicado: 2016
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5340197/
https://ncbi.nlm.nih.gov/pubmed/27284808
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02877
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