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Nucleophile-Assisted Alkene Activation: Olefins Alone Are Often Incompetent

Emerging work on organocatalytic enantioselective halocyclizations naturally draws on conditions where both new bonds must be formed under delicate control, the reaction regime where the concerted nature of the Ad(E)3 mechanism is of greatest importance. Without assistance, many simple alkene substr...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Ashtekar, Kumar Dilip, Vetticatt, Mathew, Yousefi, Roozbeh, Jackson, James E., Borhan, Babak
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5340197/
https://ncbi.nlm.nih.gov/pubmed/27284808
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02877
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