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When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides

[Image: see text] The direct introduction of the valuable SCF(3) moiety into organic molecules has received considerable attention. While it can be achieved successfully for aryl chlorides under catalysis with Ni(0)(cod)(2) and dppf, this report investigates the Ni-catalyzed functionalization of the...

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Publicat a:ACS Catal
Autors principals: Kalvet, Indrek, Guo, Qianqian, Tizzard, Graham J., Schoenebeck, Franziska
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2017
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5339856/
https://ncbi.nlm.nih.gov/pubmed/28286695
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b03344
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