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When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides

[Image: see text] The direct introduction of the valuable SCF(3) moiety into organic molecules has received considerable attention. While it can be achieved successfully for aryl chlorides under catalysis with Ni(0)(cod)(2) and dppf, this report investigates the Ni-catalyzed functionalization of the...

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Vydáno v:ACS Catal
Hlavní autoři: Kalvet, Indrek, Guo, Qianqian, Tizzard, Graham J., Schoenebeck, Franziska
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2017
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5339856/
https://ncbi.nlm.nih.gov/pubmed/28286695
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b03344
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