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Predicting solvation free energies and thermodynamics in polar solvents and mixtures using a solvation-layer interface condition

We demonstrate that with two small modifications, the popular dielectric continuum model is capable of predicting, with high accuracy, ion solvation thermodynamics (Gibbs free energies, entropies, and heat capacities) in numerous polar solvents. We are also able to predict ion solvation free energie...

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Détails bibliographiques
Publié dans:J Chem Phys
Auteurs principaux: Molavi Tabrizi, Amirhossein, Goossens, Spencer, Mehdizadeh Rahimi, Ali, Knepley, Matthew, Bardhan, Jaydeep P.
Format: Artigo
Langue:Inglês
Publié: AIP Publishing LLC 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5336475/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4977037
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