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Torsional Steering as Friend and Foe: Development of a Synthetic Route to the Briarane Diterpenoid Stereotetrad
Two synthetic routes to the briarane stereotetrad have been investigated. The first route employed a boron aldol reaction to establish the stereogenic all-carbon quaternary carbon (C1). In this case, it was found that torsional steering in the transition state led to the formation of the undesired c...
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| Publicado no: | Org Biomol Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5330299/ https://ncbi.nlm.nih.gov/pubmed/28169385 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7ob00124j |
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