Llwytho...
Enantioselective synthesis of an ophiobolin sesterterpene via a programmed radical cascade
Cyclase enzymes weave simple polyprenyl chains into the elaborate polycyclic ring systems of terpenes, a sequence that is often difficult to emulate under abiotic conditions. Herein we report a disparate synthetic approach to complex terpenes whereby simple prenyl-derived chains are cyclized using r...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Science |
|---|---|
| Prif Awduron: | , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2016
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5319821/ https://ncbi.nlm.nih.gov/pubmed/27230373 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaf6742 |
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