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KetoABNO/NO(x) Co-Catalytic Aerobic Oxidation of Aldehydes to Carboxylic Acids and Access to α-Chiral Carboxylic Acids via Sequential Asymmetric Hydroformylation/Oxidation
A method for aerobic oxidation of aldehydes to carboxylic acids has been developed using organic nitroxyl and NO(x) co-catalysts. KetoABNO (9-azabicyclo[3.3.1]nonan-3-one N-oxyl) and NaNO(2) were identified as the optimal nitroxyl and NO(x) sources, respectively. The mildness of the reaction conditi...
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| Publicado en: | Org Lett |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2016
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5279997/ https://ncbi.nlm.nih.gov/pubmed/27410397 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01598 |
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