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Alkyne Ligation Handles: Propargylation of Hydroxyl, Sulfhydryl, Amino, and Carboxyl Groups via the Nicholas Reaction
The Nicholas reaction has been applied to the installation of alkyne ligation handles. Acid-promoted propargylation of hydroxyl, sulfhydryl, amino, and carboxyl groups using dicobalt hexacarbonyl-stabilized propargylium ions is reported within. This method is especially useful for the introduction o...
שמור ב:
| הוצא לאור ב: | Org Lett |
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| Main Authors: | , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2016
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5234733/ https://ncbi.nlm.nih.gov/pubmed/27570975 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b02088 |
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