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Synthesis of Functionalized Hydrazines: Facile Homogeneous (N‐Heterocyclic Carbene)‐Palladium(0)‐Catalyzed Diboration and Silaboration of Azobenzenes

The bis(N‐heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe)(2)(PhC≡CPh)] (ITMe=1,3,4,5‐tetramethylimidazol‐2‐ylidene) acts as a highly active pre‐catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proc...

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Detalhes bibliográficos
Publicado no:Adv Synth Catal
Main Authors: Ansell, Melvyn B., Kostakis, George E., Braunschweig, Holger, Navarro, Oscar, Spencer, John
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5215626/
https://ncbi.nlm.nih.gov/pubmed/28111537
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201601106
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