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Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion

Enantioselectivity values represent relative rate measurements that are sensitive to the structural features of the substrates and catalysts interacting to produce them. Therefore, well-designed enantioselectivity data sets are information rich and can provide key insights regarding specific molecul...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Neel, Andrew J., Milo, Anat, Sigman, Matthew S., Toste, F. Dean
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5176255/
https://ncbi.nlm.nih.gov/pubmed/26967114
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b00356
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