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Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile

Kinetically-controlled catalytic cross-metathesis reactions that generate (Z)-α,β-unsaturated esters selectively are disclosed. A key finding is that the presence of acetonitrile obviates the need for using excess amounts of a more valuable terminal alkene substrates. On the basis of X-ray structure...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Yu, Elsie C., Johnson, Brett M., Townsend, Erik M., Schrock, Richard R., Hoveyda, Amir H.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5169164/
https://ncbi.nlm.nih.gov/pubmed/27634213
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608087
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