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Preparation of Macrocyclic Z-Enoates and (E,Z)- or (Z,E)-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis

[Image: see text] The first examples of catalyst-controlled stereoselective macrocyclic ring-closing metathesis reactions that generate Z-enoates as well as (E,Z)- or (Z,E)-dienoates are disclosed. Reactions promoted by 3.0–10 mol % of a Mo-based monoaryloxide pyrrolide complex proceed to completion...

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Veröffentlicht in:J Am Chem Soc
Hauptverfasser: Zhang, Hanmo, Yu, Elsie C., Torker, Sebastian, Schrock, Richard R., Hoveyda, Amir H.
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2014
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4270125/
https://ncbi.nlm.nih.gov/pubmed/25402822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja510768c
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