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Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding

[Image: see text] Azines (2,3-diazabuta-1,3-dienes) are a widely used class of compounds with conjugated C=N double bonds. Herein, we present a direct synthesis of azines from alcohols and hydrazine hydrate. The reaction, catalyzed by a ruthenium pincer complex, evolves dihydrogen and can be run in...

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Vydáno v:ACS Catal
Hlavní autoři: Bauer, Jonathan O., Leitus, Gregory, Ben-David, Yehoshoa, Milstein, David
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2016
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5152668/
https://ncbi.nlm.nih.gov/pubmed/27990319
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b02946
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