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Unified synthesis of caged Garcinia natural products based on a site-selective Claisen/Diels–Alder/Claisen rearrangement

A unified synthetic strategy toward caged Garcinia natural products has been designed and implemented. Central to the strategy is a tandem Claisen/Diels–Alder/Claisen rearrangement of a suitably substituted xanthone precursor to form forbesione (1a). Serving as a template, forbesione is then used to...

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Detalhes bibliográficos
Main Authors: Tisdale, Eric J., Slobodov, Irina, Theodorakis, Emmanuel A.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2004
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC514429/
https://ncbi.nlm.nih.gov/pubmed/15210986
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0401932101
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