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A total synthesis of estrone based on a novel cascade of radical cyclizations
Two conceptually different and novel radical-mediated cascade reactions leading to a total synthesis of the steroid (±)-estrone 1 and to a synthesis of 14-epiestrone 40 are described. Treatment of the iododienynone 23 with Bu(3)SnH/2,2′-azobis(isobutyronitrile) (AIBN) triggers a 13-endo-dig radical...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2004
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC514428/ https://ncbi.nlm.nih.gov/pubmed/15304654 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0401925101 |
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