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Gold(I)-Catalyzed Addition of Aldehydes to Cyclopropylidene Bearing 6-Aryl-1,5-Enynes()

A diastereoselective, gold-catalyzed cascading cycloisomerization of alkylidene cyclopropane bearing 1,5-enynes that terminates in a cyclo-addition of aldehydes has been developed. This diastereoselective reaction provides convergent access to novel polycyclic molecular structures (18 examples), and...

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Detalhes bibliográficos
Publicado no:Org Biomol Chem
Main Authors: Roselli, Christina A., Gagné, Michel R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5134929/
https://ncbi.nlm.nih.gov/pubmed/27853802
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6ob02128j
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