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Dehydromicrosclerodermin B and Microsclerodermin J: Total Synthesis and Structural Revision
The total synthesis of dehydromicrosclerodermin B and microsclerodermin J is described. Efficient approaches to the unusual amino acids in the target molecules were developed on the basis of a Negishi coupling (for Trp‐2‐CO(2)H) and Blaise reaction (for Pyrr). An incorrect assignment of the pyrrolid...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
John Wiley and Sons Inc.
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5132153/ https://ncbi.nlm.nih.gov/pubmed/27418203 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201604764 |
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