Dehydromicrosclerodermin B and Microsclerodermin J: Total Synthesis and Structural Revision

The total synthesis of dehydromicrosclerodermin B and microsclerodermin J is described. Efficient approaches to the unusual amino acids in the target molecules were developed on the basis of a Negishi coupling (for Trp‐2‐CO(2)H) and Blaise reaction (for Pyrr). An incorrect assignment of the pyrrolid...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Melikhova, Ekaterina Y., Pullin, Robert D. C., Winter, Christian, Donohoe, Timothy J.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2016
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5132153/
https://ncbi.nlm.nih.gov/pubmed/27418203
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201604764
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