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Total Synthesis and Structure Revision of Diplobifuranylone B

An asymmetric total synthesis of diplobifuranylone B was achieved in 10 steps for the longest linear sequence and in 15.8% overall yield from commercially available methyl (R)-(+)-lactate and l-glutamic acid. This synthesis features a stereoselective construction of the key 2,5-dihydrofuran ring in...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Cheng, Xinpeng, Quintanilla, Carlos D., Zhang, Liming
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7386208/
https://ncbi.nlm.nih.gov/pubmed/31362500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b01613
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