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The Bull-James Assembly as a Chiral Auxiliary and Shift Reagent in Kinetic Resolution of Alkyne Amines by the CuAAC Reaction()
The Bull-James boronic acid assembly is used simultaneously as a chiral auxilary for kinetic resolution and as a chiral shift reagent for in situ enantiomeric excess (ee) determination by (1)H NMR spectroscopy. Chiral terminal alkyne-containing amines, and their corresponding chiral triazoles formed...
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| Publicat a: | Org Biomol Chem |
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| Autors principals: | , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5121074/ https://ncbi.nlm.nih.gov/pubmed/27604036 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6ob01623e |
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