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Scalable procedure for the fragmentation of hydroperoxides mediated by copper and iron tetrafluoroborate salts

An improved protocol for the formal elimination of propene from organic substrates is reported. This process entails the ozonolytic conversion of an alkene to a methoxy hydroperoxide which undergoes fragmentation mediated by copper and iron. The use of soluble Cu(BF(4))(2) and Fe(BF(4))(2) results i...

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Detalhes bibliográficos
Publicado no:Org Biomol Chem
Main Authors: Huang, David, Schuppe, Alexander W., Liang, Michael Z., Newhouse, Timothy R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5111968/
https://ncbi.nlm.nih.gov/pubmed/27273761
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6ob00941g
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