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Fragmentation of β-Hydroxy Hydroperoxides

[Image: see text] A β-hydroxy hydroperoxide was obtained through base catalyzed disproportionation of a hydroperoxy endoperoxide available by singlet oxygenation of cyclohepta-1,4-diene. Vitamin E and C induce fragmentation of this β-hydroxy hydroperoxide generating aldehydes, especially in the pres...

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Detalhes bibliográficos
Main Authors: Gu, Xiaodong, Zhang, Wujuan, Salomon, Robert G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3337853/
https://ncbi.nlm.nih.gov/pubmed/22204279
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo201910g
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