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Reduction of metal adducts in oligonucleotide mass spectra in ion‐pair reversed‐phase chromatography/mass spectrometry analysis

RATIONALE: Electrospray ionization mass spectrometry (ESI‐MS)‐based techniques commonly used in oligonucleotide analyses are known to be sensitive to alkali metal adduct formation. Adducts directly impact the sensitivity of MS‐based analyses as the available charge is distributed across the parent p...

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Bibliografiske detaljer
Udgivet i:Rapid Commun Mass Spectrom
Main Authors: Birdsall, Robert E., Gilar, Martin, Shion, Henry, Yu, Ying Qing, Chen, Weibin
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5094505/
https://ncbi.nlm.nih.gov/pubmed/28328039
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/rcm.7596
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