Reduction of metal adducts in oligonucleotide mass spectra in ion‐pair reversed‐phase chromatography/mass spectrometry analysis

RATIONALE: Electrospray ionization mass spectrometry (ESI‐MS)‐based techniques commonly used in oligonucleotide analyses are known to be sensitive to alkali metal adduct formation. Adducts directly impact the sensitivity of MS‐based analyses as the available charge is distributed across the parent p...

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Detalhes bibliográficos
Publicado no:Rapid Commun Mass Spectrom
Main Authors: Birdsall, Robert E., Gilar, Martin, Shion, Henry, Yu, Ying Qing, Chen, Weibin
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5094505/
https://ncbi.nlm.nih.gov/pubmed/28328039
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/rcm.7596
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