The Simplest Amino‐borane H(2)B=NH(2) Trapped on a Rhodium Dimer: Pre‐Catalysts for Amine–Borane Dehydropolymerization

The μ‐amino–borane complexes [Rh(2)(L(R))(2)(μ‐H)(μ‐H(2)B=NHR′)][BAr(F) (4)] (L(R)=R(2)P(CH(2))(3)PR(2); R=Ph, (i)Pr; R′=H, Me) form by addition of H(3)B⋅NMeR′H(2) to [Rh(L(R))(η(6)‐C(6)H(5)F)][BAr(F) (4)]. DFT calculations demonstrate that the amino–borane interacts with the Rh centers through stro...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Kumar, Amit, Beattie, Nicholas A., Pike, Sebastian D., Macgregor, Stuart A., Weller, Andrew S.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2016
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5074255/
https://ncbi.nlm.nih.gov/pubmed/27100775
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600898
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