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The Simplest Amino‐borane H(2)B=NH(2) Trapped on a Rhodium Dimer: Pre‐Catalysts for Amine–Borane Dehydropolymerization
The μ‐amino–borane complexes [Rh(2)(L(R))(2)(μ‐H)(μ‐H(2)B=NHR′)][BAr(F) (4)] (L(R)=R(2)P(CH(2))(3)PR(2); R=Ph, (i)Pr; R′=H, Me) form by addition of H(3)B⋅NMeR′H(2) to [Rh(L(R))(η(6)‐C(6)H(5)F)][BAr(F) (4)]. DFT calculations demonstrate that the amino–borane interacts with the Rh centers through stro...
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| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5074255/ https://ncbi.nlm.nih.gov/pubmed/27100775 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600898 |
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