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A Concise Synthetic Route to the Stereotetrad Core of the Briarane Diterpenoids
A concise synthesis (under 10 steps) of the stereotetrad core of the briarane diterpenoids is reported. This approach harnesses the unique reactivity of salicylate ester derived 2,5-cyclohexadienones to quickly build complexity. In particular, a highly diastereoselective acetylide conjugate addition...
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| Publicado en: | Org Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5068569/ https://ncbi.nlm.nih.gov/pubmed/25871809 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b00816 |
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