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EXAFS reveals two Mo environments in the nitrogenase iron-molybdenum cofactor biosynthetic protein NifQ()

Mo and Fe K-edge EXAFS analysis of NifQ shows the presence of a [MoFe(3)S(4)] cluster and a second independent Mo environment that includes Mo-O bonds and Mo-S bonds. Both environments are relevant to FeMo-co biosynthesis and may represent different stages of Mo biochemical transformations catalyzed...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: George, Simon J., Hernandez, Jose A., Jimenez-Vicente, Emilio, Echavarri-Erasun, Carlos, Rubio, Luis M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5061140/
https://ncbi.nlm.nih.gov/pubmed/27711309
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc06370e
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