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EXAFS reveals two Mo environments in the nitrogenase iron-molybdenum cofactor biosynthetic protein NifQ()
Mo and Fe K-edge EXAFS analysis of NifQ shows the presence of a [MoFe(3)S(4)] cluster and a second independent Mo environment that includes Mo-O bonds and Mo-S bonds. Both environments are relevant to FeMo-co biosynthesis and may represent different stages of Mo biochemical transformations catalyzed...
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| Udgivet i: | Chem Commun (Camb) |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5061140/ https://ncbi.nlm.nih.gov/pubmed/27711309 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc06370e |
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