Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation

The synthesis of a new C (3v)‐symmetric crushed fullerene C(60)H(24) (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result i...

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Publicado no:European J Org Chem
Main Authors: Dorel, Ruth, de Mendoza, Paula, Calleja, Pilar, Pascual, Sergio, González‐Cantalapiedra, Esther, Cabello, Noemí, Echavarren, Antonio M.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5053240/
https://ncbi.nlm.nih.gov/pubmed/27774038
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201600311
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