Exceedingly Facile Ph—X Activation (X=Cl, Br, I) with Ruthenium(II): Arresting Kinetics, Autocatalysis, and Mechanisms

[(Ph(3)P)(3)Ru(L)(H)(2)] (where L=H(2) (1) in the presence of styrene, Ph(3)P (3), and N(2) (4)) cleave the Ph—X bond (X=Cl, Br, I) at RT to give [(Ph(3)P)(3)RuH(X)] (2) and PhH. A combined experimental and DFT study points to [(Ph(3)P)(3)Ru(H)(2)] as the reactive species generated upon spontaneous...

詳細記述

保存先:
書誌詳細
出版年:Angew Chem Int Ed Engl
主要な著者: Miloserdov, Fedor M., McKay, David, Muñoz, Bianca K., Samouei, Hamidreza, Macgregor, Stuart A., Grushin, Vladimir V.
フォーマット: Artigo
言語:Inglês
出版事項: WILEY‐VCH Verlag 2015
主題:
Communications
オンライン･アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5033072/
https://ncbi.nlm.nih.gov/pubmed/26036691
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501996
タグ: タグ追加
タグなし, このレコードへの初めてのタグを付けませんか!

類似資料