Exceedingly Facile Ph—X Activation (X=Cl, Br, I) with Ruthenium(II): Arresting Kinetics, Autocatalysis, and Mechanisms

[(Ph(3)P)(3)Ru(L)(H)(2)] (where L=H(2) (1) in the presence of styrene, Ph(3)P (3), and N(2) (4)) cleave the Ph—X bond (X=Cl, Br, I) at RT to give [(Ph(3)P)(3)RuH(X)] (2) and PhH. A combined experimental and DFT study points to [(Ph(3)P)(3)Ru(H)(2)] as the reactive species generated upon spontaneous...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Miloserdov, Fedor M., McKay, David, Muñoz, Bianca K., Samouei, Hamidreza, Macgregor, Stuart A., Grushin, Vladimir V.
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY‐VCH Verlag 2015
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5033072/
https://ncbi.nlm.nih.gov/pubmed/26036691
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501996
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