Photolysis of Hi-CO Nitrogenase – Observation of a Plethora of Distinct CO Species using Infrared Spectroscopy

Fourier transform infrared spectroscopy (FT-IR) was used to study the photochemistry of CO-inhibited Azotobacter vinelandii nitrogenase using visible light at cryogenic temperatures. The FT-IR difference spectrum of photolyzed hi-CO at 4 K comprises negative bands at 1973 cm(−1) and 1679 cm(−1) toge...

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Detalhes bibliográficos
Publicado no:Eur J Inorg Chem
Main Authors: Yan, Lifen, Dapper, Christie H., George, Simon J., Wang, Hongxin, Mitra, Devrani, Dong, Weibing, Newton, William E., Cramer, Stephen P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5019582/
https://ncbi.nlm.nih.gov/pubmed/27630531
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201100029
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