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IR-Monitored Photolysis of CO-Inhibited Nitrogenase: A Major EPR-Silent Species with Coupled Terminal CO Ligands

We have used Fourier transform infrared spectroscopy (FT-IR) to observe the photolysis and recombination of a novel EPR-silent CO-inhibited form of α-H195Q nitrogenase from Azotobacter vinelandii. Photolysis at 4 K yields a strong negative IR difference band at 1938 cm(−1), along with a weaker negat...

詳細記述

保存先:
書誌詳細
出版年:Chemistry
主要な著者: Yan, Lifen, Pelmenschikov, Vladimir, Dapper, Christie H., Scott, Aubrey D., Newton, William E., Cramer, Stephen P.
フォーマット: Artigo
言語:Inglês
出版事項: 2012
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4497518/
https://ncbi.nlm.nih.gov/pubmed/23136072
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201202072
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