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Synthesis and Properties of “Sandwich” Diimine-Coinage Metal Ethylene Complexes

Synthesis and full characterization of cationic isostructural “sandwich” diimine-coinage metal ethylene complexes are reported. Ethylene self-exchange kinetics proceeds by an associative exchange mechanism for Cu and Au complexes. The fastest ligand exchange was observed for Ag complex 8a. The upper...

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Publicado en:Organometallics
Autores principales: Klimovica, Kristine, Kirschbaum, Kristin, Daugulis, Olafs
Formato: Artigo
Lenguaje:Inglês
Publicado: 2016
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5019172/
https://ncbi.nlm.nih.gov/pubmed/27642213
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.6b00487
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