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Copper-Catalyzed, Directing Group-Assisted Fluorination of Arene and Heteroarene C-H Bonds
We have developed a method for direct, copper-catalyzed, auxiliary-assisted fluorination of β-sp(2) C-H bonds of benzoic acid derivatives and γ-sp(2) C-H bonds of α,α-disubstituted benzylamine derivatives. The reaction employs CuI catalyst, AgF fluoride source, and DMF, pyridine, or DMPU solvent at...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3733384/ https://ncbi.nlm.nih.gov/pubmed/23758609 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4047125 |
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