Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides via Co(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures

Co(II)-based metalloradical catalysis (MRC) has been successfully applied for effective construction of the highly strained 2-sulfonyl-1,3-diazabicyclo[3.1.0]-hexane structures in high yields through intramolecular radical aziridination of allylic sulfamoyl azides. The resulting [3.1.0]-bicyclic azi...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Jiang, Huiling, Lang, Kai, Lu, Hongjian, Wojtas, Lukasz, Peter Zhang, X.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5014589/
https://ncbi.nlm.nih.gov/pubmed/27511474
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201605238
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