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The Competing Mechanisms of Phosphate Monoester Dianion Hydrolysis

[Image: see text] Despite the numerous experimental and theoretical studies on phosphate monoester hydrolysis, significant questions remain concerning the mechanistic details of these biologically critical reactions. In the present work we construct a linear free energy relationship for phosphate mo...

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Dettagli Bibliografici
Pubblicato in:J Am Chem Soc
Autori principali: Duarte, Fernanda, Barrozo, Alexandre, Åqvist, Johan, Williams, Nicholas H., Kamerlin, Shina C. L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2016
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4999962/
https://ncbi.nlm.nih.gov/pubmed/27471914
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b06277
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