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Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic Acid
Carboxylic acids effectively direct C-H activation for Rhodium(III)-catalyzed intramolecular Heck-type reactions. A catalytic amount of Cu(OAc)(2) is used as the external oxidant with oxygen likely acting as the terminal oxidant. Additionally, a novel electron-deficient Rh(III) catalyst was found to...
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| Publicado no: | Synlett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4986923/ https://ncbi.nlm.nih.gov/pubmed/27540274 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0034-1381006 |
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